Metrika članka

  • citati u SCindeksu: 0
  • citati u Google Scholaru:[=>]
  • posete u prethodnih 30 dana:3
  • preuzimanja u prethodnih 30 dana:2
članak: 1 od 1  
Recycling and Sustainable Development
2016, vol. 9, br. 1, str. 28-46
jezik rada: srpski
pregledni članak
doi:10.5937/ror1601028C

Creative Commons License 4.0
Nusproizvodi procesa rafinacije jestivih ulja kao sirovine za dobijanje biodizela
aVictoriaoil, Šid
bUniverzitet u Nišu, Tehnološki fakultet, Leskovac

e-adresa: veljkovicvb@yahoo.com

Projekat

Nanostrukturni funkcionalni i kompozitni materijali u katalitickim i sorpcionim procesima (MPNTR - 45001)

Sažetak

Biodizel, altemativno gorivo fosilnim, dobija se reakcijom transesteriíikacije triacilglicerola iz biljnih ulja i životinjskih masti nižim alifatičnim alkoholima. I pored brojnih prednosti u odnosu na fosilna goriva, glavna prepreka široj komercijalnoj upotrebi biodizela je visoka cena jestivih biljnih ulja. U poslednje vreme, posebnu pažnju zaslužuju nusproizvodi industrije proizvodnje jestivih ulja kao izvori triacilglicerola, jer se njihovim korišćenjem ostvaruju pozitivni ekonomski i ekološki efekti. U radu su analizirani postupci dobijanja biodizela iz nusproizvoda procesa rafinacije jestivih ulja (sapunske smeše, otpadna zemlja za beljenje, deodorisani destilat), sa osvrtom na faktore koji utiču na reakciju sinteze estara masnih kiselina. Cilj rada je da se istraže mogućnosti korišćenja ovih otpadnih sirovina u proizvodnji biodizela.

Ključne reči

biodizel; deodorisani destilat; jestiva ulja; otpadna zemlja za beljenje; rafinacija; sapunske smeše

Reference

Akgün, N., Yaprakçı, A., Candemir, C. (2010) Esterification of olive acid oil in supercritical methanol. European Journal of Lipid Science and Technology, 112, 593-599
Barrera-Arellano, D., Facioli, N.L. (2002) Optimization of direct acid esterification process of soybean oil deodorizer distillate. Grasas y Aceites, 53(2): 206-212
Bournay, L., Casanave, D., Delfort, B., Hillion, G., Chodorge, J.A. (2005) New heterogeneous process for biodiesel production: A way to improve the quality and the value of the crude glycerin produced by biodiesel plants. Catalysis Today, 106(1-4): 190-192
Canakci, M. (2007) The potential of restaurant waste lipids as biodiesel feedstocks. Bioresource technology / Bioresour. Technol., 98(1): 183-90
Chang, J.I., Tai, H., Huang, T. (2006) Regeneration of spent bleaching earth by lye-extraction. Environmental Progress, 25(4): 373-378
Cheah, K.Y., Siew, W.L. (2004) Regeneration of spent bleaching clay. MPOB TT, Malaysian Palm Oil Board (MPOB) Information Series 237, No. 230, http://palmoilis.mpob.gov.my/publications/TOT/TT-230.pdf
Chen, X., Du, W., Liu, D. (2008) Response surface optimization of biocatalytic biodiesel production with acid oil. Biochemical Engineering Journal, 40(3): 423-429
Chen, Y., Xiao, B., Chang, J., Fu, Y., Lv, P., Wang, X. (2009) Synthesis of biodiesel from waste cooking oil using immobilized lipase in fixed bed reactor. Energy Conversion and Management, 50(3): 668-673
Chongkhong, S., Tongurai, C., Chetpattananondh, P., Bunyakan, C. (2007) Biodiesel production by esterification of palm fatty acid distillate. Biomass and Bioenergy, 31(8): 563-568
Chongkhong, S., Tongurai, C., Chetpattananondh, P. (2009) Continuous esterification for biodiesel production from palm fatty acid distillate using economical process. Renewable Energy, 34(4): 1059-1063
Corrêa, I.N.dos S., de Souza, S.L., Catran, M., Bernardes, O.L., Portilho, M.F., Langone, M.A.P. (2011) Enzymatic Biodiesel Synthesis Using a Byproduct Obtained from Palm Oil Refining. Enzyme Research, 2011: 1-8
Domingues, C., Correia, M.N., Carvalho, R., Henriques, C., Bordado, J., Dias, A.P.S. (2013) Vanadium phosphate catalysts for biodiesel production from acid industrial by-products. Journal of biotechnology / J. Biotechnol., 164(3): 433-40
Du, W., Wang, L., Liu, D. (2007) Improved methanol tolerance during Novozym435-mediated methanolysis of SODD for biodiesel production. Green Chem., 9(2): 173-176
Eaves, P.H., Spadaro, J. J., Gastrock, E. A. (1959) Methyl esters directlyfrom acidulated soapstock. Journal of the American Oil Chemists Society, 36(6): 230-234
Echim, C., Verhé, R., de Greyt, W., Stevens, C. (2009) Production of biodiesel from side-stream refining products. Energy & Environmental Science, 2(11): 1131
Facioli, N.L., Barrera-Arellano, D. (2001) Optimisation of enzymatic esterification of soybean oil deodoriser distillate. Journal of the Science of Food and Agriculture, 81(12): 1193-1198
Felizardo, P., Machado, J., Vergueiro, D., Correia, M. J.N., Gomes, J.P., Bordado, J.M. (2011) Study on the glycerolysis reaction of high free fatty acid oils for use as biodiesel feedstock. Fuel Processing Technology, 92(6): 1225-1229
Gül, Ö. F., Tüter, M., Aksoy, H. A. (2010) The Utilization of Waste Activated Bleaching Earth in Biodiesel Production: Optimization by Response Surface Methodology. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 32(19): 1812-1820
Guo, F., Xiu, Z., Liang, Z. (2012) Synthesis of biodiesel from acidified soybean soapstock using a lignin-derived carbonaceous catalyst. Applied Energy, 98: 47-52
Haas, M.J., Michalski, P.J., Runyon, S., Nunez, A., Scott, K.M. (2003) Production of FAME from acid oil, a byproduct of vegetable oil refining. Journal of the American Oil Chemists Society, 97-102; 80
Haas, M.J. (2005) Improving the economics of biodiesel production through the use of low value lipids as feedstocks: vegetable oil soapstock. Fuel Processing Technology, 86(10): 1087-1096
Haas, M.J., Scott, K.M. (1996) Combined nonenzymatic-enzymatic method for the synthesis of simple alkyl fatty acid esters from soapstock. Journal of the American Oil Chemists’ Society, 73(11): 1393-1401
Haas, M.J., Bloomer, S., Scott, K. (2000) Simple, high-efficiency synthesis of fatty acid methyl esters from soapstock. Journal of the American Oil Chemists' Society, 77(4): 373-379
Huang, Y., Chang, J.I. (2010) Biodiesel production from residual oils recovered from spent bleaching earth. Renewable Energy, 35(1): 269-274
Jin, B., Zhu, M., Fan, P., Yu, L.-J. (2008) Comprehensive utilization of the mixture of oil sediments and soapstocks for producing FAME and phosphatides. Fuel Processing Technology, 89(1): 77-82
Keskin, A., Gürü, M., Altiparmak, D., Aydin, K. (2008) Using of cotton oil soapstock biodiesel–diesel fuel blends as an alternative diesel fuel. Renewable Energy, 33(4): 553-557
Kheang, L.S., Foon, C.T., May, C.Y., Ngan, M.A. (2006) A study of residual oils recovered from spent bleaching earth: their characteristics and applications. American Journal of Applied Science, 3, 2063-2067
Kheang, L.S., Foon, C.S., May, C.Y., Ngan, M.A. (2006) A Study of Residual Oils Recovered from Spent Bleaching Earth: Their Characteristics and Applications. American Journal of Applied Sciences, 3(10): 2063-2067
King, J.W., List, G.R., Johnson, J.H. (1992) Supercritical carbon dioxide extraction of spent bleaching clays. Journal of Supercritical Fluids, 5(1): 38-41
Kojima, S., Du, D., Sato, M., Park, E.Y. (2004) Efficient production of fatty acid methyl ester from waste activated bleaching earth using diesel oil as organic solvent. Journal of Bioscience and Bioengineering, 98(6): 420-424
Kusdiana, D., Saka, S. (2004) Two-Step Preparation for Catalyst-Free Biodiesel Fuel Production: Hydrolysis and Methyl Esterification. Applied Biochemistry and Biotechnology, 115(1-3): 0781-0792
Lara, P., Park, E.Y. (2004) Potential application of waste activated bleaching earth on the production of fatty acid alkyl esters using Candida cylindracea lipase in organic solvent system. Enzyme and Microbial Technology, 34(3-4): 270-277
Li, Y., Zhang, X., Sun, L. (2010) Fatty acid methyl esters from soapstocks with potential use as biodiesel. Energy Conversion and Management, 51(11): 2307-2311
Lim, B.P., Maniam, G.P., Hamid, S.A. (2009) Biodiesel from adsorbed waste oil on spent bleaching clay using CaO as a heterogeneous catalyst. European Journal of Scientific Research, 347-357; 33
Liu, Y., Wang, L. (2009) Biodiesel production from rapeseed deodorizer distillate in a packed column reactor. Chemical Engineering and Processing: Process Intensification, 48(6): 1152-1156
Liu, Y., Wang, L., Yan, Y. (2009) Biodiesel synthesis combining pre-esterification with alkali catalyzed process from rapeseed oil deodorizer distillate. Fuel Processing Technology, 90(7-8): 857-862
Lo, S. K., Baharin, B. S., Tan, C. P., Lai, O. M. (2004) Enzyme-Catalyzed Production and Chemical Composition of Diacylglycerols from Corn Oil Deodorizer Distillate. Food Biotechnology, 18(3): 265-278
Luxem, F.J., Troy, W.M. (2004) Method of making alkyl esters using pressure. US Patent 6768015, Res. 550-553, 687-692
Luxem, F.J., Mirous, B.K. (2008) Biodiesel from acidulated soapstock. u: Hou C.T., Shaw J.F. [ur.] Biocatalysis and Bioenergy, John Wiley & Sons, 115-29
Mat, R., Ling, O.S., Johari, A., Mohammed, M. (2011) In Situ Biodiesel Production from Residual Oil Recovered from Spent Bleaching Earth. Bulletin of Chemical Reaction Engineering & Catalysis, 6(1)
McNeff, C.V., McNeff, L.C., Yan, B., Nowlan, D.T., Rasmussen, M., Gyberg, A.E., Krohn, B.J., Fedie, R.L., Hoye, T.R. (2008) A continuous catalytic system for biodiesel production. Applied Catalysis A: General, 343(1-2): 39-48
Nagesha, G.K., Manohar, B., Sankar, K. U. (2004) Enzymatic esterification of free fatty acids of hydrolyzed soy deodorizer distillate in supercritical carbon dioxide. Journal of Supercritical Fluids, 32(1-3): 137-145
Park, E.Y., Sato, M., Kojima, S. (2008) Lipase-catalyzed biodiesel production from waste activated bleaching earth as raw material in a pilot plant. Bioresource technology / Bioresour. Technol., 99(8): 3130-5
Park, J., Wang, Z., Kim, D., Lee, J. (2010) Effects of water on the esterification of free fatty acids by acid catalysts. Renewable Energy, 35(3): 614-618
Park, J., Kim, D., Wang, Z., Lee, J., Park, S., Lee, J. (2008) Production of biodiesel from soapstock using an ion-exchange resin catalyst. Korean Journal of Chemical Engineering, 25(6): 1350-1354
Pinnarat, T., Savage, P.E. (2008) Assessment of Noncatalytic Biodiesel Synthesis Using Supercritical Reaction Conditions. Industrial & Engineering Chemistry Research, 47(18): 6801-6808
Pizarro, A.V.L., Park, E.Y. (2003) Lipase-catalyzed production of biodiesel fuel from vegetable oils contained in waste activated bleaching earth. Process Biochemistry, 38(7): 1077-1082
Ramamurthi, S., Bhirud, P.R., McCurdy, A.R. (1991) Enzymatic methylation of canola oil deodorizer distillate. Journal of the American Oil Chemists Society, 68(12): 970-975
Shao, P., He, J., Sun, P., Jiang, S. (2009) Process optimisation for the production of biodiesel from rapeseed soapstock by a novel method of short path distillation. Biosystems Engineering, 102(3): 285-290
Shao, P., Meng, X., He, J., Sun, P. (2008) Analysis of immobilized Candida rugosa lipase catalyzed preparation of biodiesel from rapeseed soapstock. Food and Bioproducts Processing, 86(4): 283-289
Singh, A., He, B., Thompson, J., van Gerpen, J. (2006) Process optimization of biodiesel production using alkaline catalysts. Applied Engineering in Agriculture, 22(4): 597-600
Souza, M.S., Aguieiras, E.C. G., Silva, M.A. P. da, Langone, M.A. P. (2008) Biodiesel Synthesis via Esterification of Feedstock with High Content of Free Fatty Acids. Applied Biochemistry and Biotechnology, 154(1-3): 74-88
Stamenković, I. (2016) Nusproizvodi procesa rafinacije jestivog ulja kao sirovina za dobijanje biodizela. Niš: Tehnološki fakultet u Leskovcu, diplomski rad
Talukder, M. M. R., Wu, J. C., Lau, S. K., Cui, L. C., Shimin, G., Lim, A. (2009) Comparison of Novozym 435 and Amberlyst 15 as Heterogeneous Catalyst for Production of Biodiesel from Palm Fatty Acid Distillate. Energy & Fuels, 23(1): 1-4
Tüter, M., Aksoy, H. A., Gılbaz, E. E., Kurşun, E. (2004) Synthesis of fatty acid esters from acid oils using lipase B fromCandida antarctica. European Journal of Lipid Science and Technology, 106(8): 513-517
van Kasteren, J.M.N., Nisworo, A.P. (2007) A process model to estimate the cost of industrial scale biodiesel production from waste cooking oil by supercritical transesterification. Resources, Conservation and Recycling, 50(4): 442-458
Veljković, V.B., Banković-Ilić, I.B., Stamenković, O.S., Hung, Y.T. (2017) Waste vegetable oils, fats and cooking oils in biodiesel production. u: Wang L.K., Wang M.H.S., Shammas N.K., Hung Y.T., Chen J.P. [ur.] Handbook of Advanced Industrial and Hazardous Wastes Management, Boca Raton - London - New York: CRC Press Taylor and Francis Group press
Verhé, R., van Hoed, V., Echim, C., Stevens, C., de Greyt, W., Kellens, M. (2008) Production of biofuel from lipids and alternative resources. u: Hou C.T., Shaw J.F. [ur.] Biocatalysis and Bioenergy, Hoboken: John Wiley & Sons, 185-95
Wang, L., Du, W., Liu, D., Li, L., Dai, N. (2006) Lipase-catalyzed biodiesel production from soybean oil deodorizer distillate with absorbent present in tert-butanol system. Journal of Molecular Catalysis B: Enzymatic, 43(1-4): 29-32
Wang, Z., Lee, J., Park, J., Wu, C., Yuan, Z. (2007) Novel biodiesel production technology from soybean soapstock. Korean Journal of Chemical Engineering, 24(6): 1027-1030
Watanabe, Y., Nagao, T., Nishida, Y., Takagi, Y., Shimada, Y. (2007) Enzymatic Production of Fatty Acid Methyl Esters by Hydrolysis of Acid Oil Followed by Esterification. Journal of the American Oil Chemists' Society, 84(11): 1015-1021
Watanabe, Y., Pinsirodom, P., Nagao, T., Yamauchi, A., Kobayashi, T., Nishida, Y., Takagi, Y., Shimada, Y. (2007) Conversion of acid oil by-produced in vegetable oil refining to biodiesel fuel by immobilized Candida antarctica lipase. Journal of Molecular Catalysis B: Enzymatic, 44(3-4): 99-105
Xi, L.M., Cao, S.Y. (2011) Synthesis of Biodiesel from by-Product of Plant Oil by the Catalysis of Solid Acid in Fixed Bed. Advanced Materials Research, 322: 15-20
Yoo, C.K., Lin, S.W. (2004) Regeneration of spent bleaching clay. MPOB TT, No. 230, Kuala Lumpur: Malaysian Palm Oil Board, Ministry of Plantation Industries and Communities