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Journal of the Serbian Chemical Society
2008, vol. 73, br. 4, str. 423-429
jezik rada: engleski
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doi:10.2298/JSC0804423K

Metalni kompleksi sa Šifovim bazama dobijenim od dicinamoilmetana i alifatičnih diamina
aDepartment of Chemistry, University of Calicut, Kerala, India
bDepartment of Chemistry, NSS College, Manjeri, Kerala, India
cDepartment of Chemistry, Unity Women’s College, Manjeri, Kerala, India

e-adresa: mbummathur@rediffmail.com

Sažetak

Dve nove Šifove baze koje sadrže olefinske veze sintetisane su pod određenim uslovima kondenzacijom alifatičnih diamina i dicinamoilmetana. Pokazano je IC, 1HNMR i masenim spektralnim podacima da su ova jedinjenja pretežno u keto-enaminskoj formi, sa intramolekulskom vezom preko vodonika. Na osnovu analitičkih i spektralnih podataka ustanovljena je dvobazna tetradentatna N2O2 koordinacija ovih jedinjenja u [ML] kompleksima (M = Ni(II), Cu(II) i Zn(II)).

Ključne reči

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