članak: 1 od 1  
Journal of the Serbian Chemical Society
2010, vol. 75, br. 7, str. 997-1003
jezik rada: engleski
izvorni naučni članak
doi:10.2298/JSC091123067J

Pouzdan model za predskazivanje toplote isparavanja n-alkana na 298,15 K
Univerzitet u Beogradu, Tehnološko-metalurški fakultet

e-adresa: dule@tmf.bg.ac.rs

Sažetak

U ovom radu predložen je pouzdan model za procenu vrednosti toplote isparavanja n-alkana na temperaturi 298,15 K sa brojem ugljenikovih atoma i normalnom temperaturom ključanja, kao jedinim potrebnim vrednostima. Predloženi model upoređen je sa postojećim odgovarajućim modelima i dao je najbolje, kako srednje procentualno odstupanje 0,81 %, tako i najmanju vrednost maksimalnog procentualnog odstupanja 2,93 %.

Ključne reči

Reference

Abramzon, A.A. (1967) Zh. prikl. khim, 40, 2598
Chickos, J.S., Wilson, J.A. (1997) Journal of Chemical & Engineering Data, 42(1): 190
Chickos, J.S., Hanshaw, W. (2004) Journal of Chemical & Engineering Data, 49(1): 77
Chickos, J.S., Hanshaw, W. (2004) Vapor Pressures and Vaporization Enthalpies of the n-Alkanes from C31 to C38 at T = 29815 K by Correlation Gas Chromatography. Journal of Chemical and Engineering Data, 49(3), 620-630
Chickos, J.S., Hyman, A.S., Ladon, L.H., Liebman, J.F. (1981) Measurement and estimation of the heats of vaporization of hydrocarbons. Journal of Organic Chemistry, 46(21), 4294-6
Constantinou, L., Gani, R. (1994) New group contribution method for estimating properties of pure compounds. AIChE Journal, 40, 1697-710
da Silva, R.M.A.V., Matos, M.A.R., Amaral, L.M.P.F. (1995) Journal of Chemical Thermodynamics, 27(6): 565
da Silva, R.M.A.V., Ferrao, M.L.C.C.H., Jiye, F. (1995) Journal of Chemical & Engineering Data, 40(2): 426
Douglas, T.B., Furukawa, G.T., McCoskey, R.E., Ball, A.F. (1954) Calorimetric properties of normal heptane from 0 to 520 K. J Res. NBS, 53, 139-153
Ducros, M., Gruson, J.F., Sannier, H. (1980) Thermochimica Acta, 36(1): 39
Ducros, M., Gruson, J.F., Sannier, H. (1981) Thermochimica Acta, 44(2): 131
Ducros, M., Sannier, H. (1982) Thermochimica Acta, 54(1-2): 153
Ducros, M., Sannier, H. (1984) Thermochimica Acta, 75(3): 329
Dunkel, M. (1928) Z. physik. Chem, A138, 42
Fenwick, J.O., Harrop, D., Head, A.J. (1975) Journal of Chemical Thermodynamics, 7(10): 943
Fuchs, R., Peacock, L.A., Stephenson, W.K. (1982) Canadian Journal of Chemistry, 60(15): 1953
Fuchs, R., Peacock, L.A. (1980) Canadian Journal of Chemistry, 58(24): 2796
Furukawa, J., Sakiyama, M., Seki, S., Saito, Y., Kusano, K. (1982) Bulletin of the Chemical Society of Japan, 55(10): 3329
Gamba, S., Soave, G.S., Pellegrini, L.A. (2009) Fluid Phase Equilibria, 276(2): 133
Guthrie, J.P., Taylor, K.F. (1983) Canadian Journal of Chemistry, 61(3): 602
Hallman, J.H., Stephenson, W.K., Fuchs, R. (1983) Canadian Journal of Chemistry, 61(9): 2044
Hossenlopp, I.A., Scott, D.W. (1981) Journal of Chemical Thermodynamics, 13(5): 415
Irving, R.J. (1972) Journal of Chemical Thermodynamics, 4(5): 793
Klages, F. (1949) Chemische Berichte, 82(4-5): 358
Kolská, Z., Růzička, V., Gani, R. (2005) Industrial & Engineering Chemistry Research, 44(22): 8436
Kusano, K. (1985) Thermochimica Acta, 88(1): 109
Laidler, K.J. (1956) Canadian Journal of Chemistry, 34(5): 626
Lebedev, V.P., Miroshnichenko, E.A., Matyushin, Y.N., Larionov, B.P., Romanov, V.S., Bukolov, Y.E., Denisov, G.M., Balepin, A.A., Lebedev, Y.A. (1975) Semimicrocalorimetric determination of the enthalpy of formation of nitrogen-oxygen containing compounds in the gas phase II. Calorimetric determination of the enthalpy of formation. Zhurnal Fizicheskoi Khimii, 49(8), 1928-32
Lemons, J.F., Felsing, W.A. (1943) Journal of the American Chemical Society, 65(1): 46
Lovering, E.G., Laidler, K.J. (1960) Canadian Journal of Chemistry, 38(12): 2367
Lovering, E.G., Nor, O.M. (1962) Canadian Journal of Chemistry, 40(2): 199
Majer, V., Svoboda, V., Hala, S., Pick, J. (1979) Temperature dependence of heats of vaporization of saturated hydrocarbons c5-c8: Experimental data and an estimation method. Collection of Czechoslovak Chemical Communications, 44, 637-651
Månsson, M., Sellers, P., Stridh, G., Sunner, S. (1977) Journal of Chemical Thermodynamics, 9(1): 91
Marano, J.J., Holder, G.D. (1997) Industrial & Engineering Chemistry Research, 36(6): 2399
Marrero, J., Gani, R. (2001) Group-contribution based estimation of pure component properties. Fluid Phase Equilibria, 183-184, 183-208
Mccurdy, K.G., Laidler, K.J. (1963) Canadian Journal of Chemistry, 41(8): 1867
Melaugh, R.A., Mansson, M., Rossini, F.D. (1976) Journal of Chemical Thermodynamics, 8(7): 623
Messerly, G.H., Kennedy, R.M. (1940) J Am Chem Soc, 62, 2988
Morawetz, E. (1972) Journal of Chemical Thermodynamics, 4(1): 139
Morawetz, E., Sunner, S. (1963) Design, construction, and testing of a heat of vaporization calorimeter useful in the vapor pressure range 1 to 001 mm. Hg at 25.degree. Acta Chemica Scandinavica, 17, 473-88
Morawetz, E. (1968) Acta Chem. Scand, 22; 1509
Osborne, N.S., Ginnings, D.C. (1947) Measurements of heat of vaporization and heat capacity of a number of hydrocarbons. J Res. NBS, 39, 453-477
Phillips, J.C. (1998) Enthalpies of vaporization of oligomers of poly(hexamethylene sebacate) and esters of alkylcarboxylic acids. Journal of Applied Polymer Science, 70(4), 731-746
Varushchenko, R.M., Gal, G.L., Medvedev, V.A. (1977) Precision calorimetric apparatus for determining enthalpies of evaporation. Zhurnal Fizicheskoi Khimii, 51(4), 992-6
Waddington, G., Douslin, D.R. (1947) Journal of the American Chemical Society, 69(10): 2275
Wadso, I. (1966) A heat of vaporization calorimeter for work at 25 degrees C and for small amounts of substances. Acta Chemica Scandinavica, 20: 536
Wadso, I. (1960) An adiabatic calorimeter for measuring heats of vaporization at 25 degrees C. Acta Chemica Scandinavica, 14: 566
Wall, L.A., Flynn, J.H., Straus, S. (1970) Journal of Physical Chemistry, 74(17): 3237