članak: 1 od 1  
Journal of the Serbian Chemical Society
2011, vol. 76, br. 9, str. 1295-1305
jezik rada: engleski
izvorni naučni članak
doi:10.2298/JSC100826114A

Senzor za lutecijum na bazi (2-okso-1,2-difeniletiliden)-N-fenilhidrazinkarbotioamida u PVC matrici
aDepartment of Applied Chemistry, Quchan branch, Islamic Azad University, Quchan, Iran
bCenter of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran
cEndocrinology and Metabolism Research Center, Tehran University of Medical Sciences, Tehran, Iran

e-adresa: haszamani@yahoo.com

Sažetak

Na osnovu ranijeg iskustva u dizajnu i konstrukciji senzora za jone metala, posebno onih visoke osetljivosti za lantanoide, napravljen je senzor za Lu3+ na bazi (2-okso-1,2-difeniletiliden)-N-fenilhidrazinkarbotioamid (PHCT) u PVC matrici, koji je pokazao Nernstov nagib od 19,8±0,3 mV dek-1. Pokazano je da senzor radi dobro u opsegu koncentracija Lu3+ od 1,0×10-2 do 1,0×10-6 mol L-1 i da mu je granica osetljivosti 6,8×10-7 mol L-1. Selektivnost senzora prema mnogim uobičajenim alkalnim, zemnoalkalnim, prelaznim i teškim metalima, a posebno prema jonima lantanoida je veoma dobra i može se upotrebljavati u opsegu pH 2,5-8,7. Sa periodom upotrebe od najmanje 2 meseca i kratkim vremenom odziva od ≈5 s, senzor je uspešno korišćen kao indikatroska elektroda u potenciometrijskoj titraciji Lu3+.

Ključne reči

potentiometry; sensor; PVC membrane; ion-selective electrode

Reference

Abedi, M.R., Zamani, H.A., Ganjali, M.R., Norouzi, P. (2007) Cr(III) Ion-Selective Membrane Sensor Based on 1,3-Diamino-2-Hydroxypropane-N,N,N',N' Tetraacetic Acid. Sensor Letters, 5(3): 516-521
Ali, Z.H., Masrournia, M., Sahebnasagh, S., Reza, G.M. (2009) Analytical Letters, 42(3): 555-570
Ammann, D., Pretsch, E., Simon, W., Lindner, E., Bezegh, A., Pungor, E. (1985) Lipophilic salts as membrane additives and their influence on the properties of macro- and micro-electrodes based on neutral carriers. Analytica Chimica Acta, 171: 119-129
Bariain, C., Matias, I.R., Fernandez-Valdivielso, C., Arregui, F.J., Rodriguez-Mendezb, M.L., de Saja, J.A. (2003) Optical fiber sensor based on lutetium bisphthalocyanine for the detection of gases using standard telecommunication wavelengths. Sensors and Actuators B: Chemical, 93(1-3): 153-158
Behmadi, H., Zamani, H., Ganjali, M., Norouzi, P. (2007) Determination of neodymium(III) ions in soil and sediment samples by a novel neodymium(III) sensor based on benzyl bisthiosemicarbazone. Electrochimica Acta, 53(4): 1870-1876
Faridbod, F., Ganjali, M.R., Labbafi, S., Norouzi, P. (2008) Lanthanide Recognition: Development of an Asymetric Gadolinium Microsensor Based on N-(2-pyridyl)-N-(4-nitrophenyl)thiourea. Analytical Letters, 41(16): 2972-2984
Faridbod, F., Ganjali, M.R., Larijani, B., Norouzi, P. (2009) Multi-walled carbon nanotubes (MWCNTs) and room temperature ionic liquids (RTILs) carbon paste Er(III) sensor based on a new derivative of dansyl chloride. Electrochimica Acta, 55(1): 234-239
Faridbod, F., Ganjali, M.R., Dinarvand, R., Norouzi, P. (2007) Ion Recognition: Application of Symmetric and Asymmetric Schiff Bases and Their Complexes for the Fabrication of Cationic and Anionic Membrane Sensors to Determine Ions in Real Samples. Combinatorial Chemistry & High Throughput Screening, 10(7): 527-546
Ganjali, M., Norouzi, P., Atrian, A., Faridbod, F., Meghdadi, S., Giahi, M. (2009) Neutral N,N'-bis(2-pyridinecarboxamide)-1,2-ethane as sensing material for determination of lutetium(III) ions in biological and environmental samples. Materials Science and Engineering: C, 29(1): 205-210
Ganjali, M.R., Norouzi, P., Faridbod, F., Ghorbani, M., Adib, M. (2008) Anal. Chim. Acta, 569: 35
Ganjali, M.R., Tamaddon, A., Norouzi, P., Adib, M. (2006) Novel Lu(III) membrane sensor based on a new asymmetrically S-N Schiff's base. Sensors and Actuators B: Chemical, 120(1): 194-199
Ganjali, M.R., Memari, Z., Faridbod, F., Dinarvand, R., Norouzi, P. (2008) Electroanalysis, 20(24): 2663-2670
Gupta, J.G. (1993) Determination of scandium, yttrium and eight rare earth elements in silicate rocks and six new geological reference materials by simultaneous multi-element electrothermal atomic absorption spectrometry with Zeeman-effect background correction. Journal of Analytical Atomic Spectrometry, 8(1): 93
Gupta, V.K., Pal, M.K., Singh, A.K. (2009) Comparative evaluation of Dy(III) selective poly(vinyl) chloride based membrane electrodes of macrocyclic tetraimine Schiff's bases. Talanta, 79(2): 528-33
Gupta, V.K., Goyal, R.N., Pal, M.K., Sharma, R.A. (2009) Comparative studies of praseodymium(III) selective sensors based on newly synthesized Schiff's bases. Analytica chimica acta, 653(2): 161-6
Huster, M., Gehring, P.M., Morf, W.E., Simon, W. (1990) Anal. Chem, 63: 1330
Jain, A.K., Gupta, V.K., Singh, L.P., Khurana, U. (1997) Macrocycle Based Membrane Sensors for the Determination of Cobalt(II) Ions. Analyst, 122(6): 583-586
Kamata, Satsuo., Bhale, Ajay., Fukunaga, Yumi., Murata, Hiroyuki. (1988) Copper(II)-selective electrode using thiuram disulfide neutral carriers. Analytical Chemistry, 60(22): 2464-2467
Liu, L., Wang, L., Yin, H., Li, Y., He, X. (2006) The Preparation and Application of Bismuth (III) Ion-Selective Electrode Based on Nanoparticles of Bismuth Sulfide. Analytical Letters, 39(5): 879-890
Luo, E.P., Chai, Y.Q., Yuan, R. (2007) Unsymmetrical Tetradentate Schiff Bases Copper (II) Complex as Neutral Carrier for Thiocyanate Selective Electrode. Analytical Letters, 40(2): 369-386
Mohammadhossieni, M., Ali, Z.H., Nekoei, M. (2009) Terbium(III) Ion-Selective Electrochemical Sensor Based on Hematoporphyrin. Analytical Letters, 42(2): 298-311
Naddaf, E., Zamani, H.A. (2009) Samarium(III)-PVC-Membrane Sensor Based on Ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline. Analytical Letters, 42(17): 2838-2852
Nekoei, M., Zamani, H.A., Mohammadhossieni, M. (2009) Erbium(III) PVC Membrane Ion-Selective Sensor based on 4-(2-Thiazolylazo)resorcinal. Analytical Letters, 42(2): 284-297
Prasad, R., Gupta, V.K., Kumar, A. (2004) Metallo-tetraazaporphyrin based anion sensors: regulation of sensor characteristics through central metal ion coordination. Analytica Chimica Acta, 508(1): 61-70
Reza, G.M., Norouzi, P., Faridbod, F., Hajiabdollah, N., Dinarvand, R., Meghdadi, S. (2008) Analytical Letters, 41(1): 3-23
Rosatzin, T., Bakker, E., Suzuki, K., Simon, W. (1993) Lipophilic and immobilized anionic additives in solvent polymeric membranes of cation-selective chemical sensors. Analytica Chimica Acta, 280(2): 197-208
Saleh, M.B., Soliman, E.M., Abdel, G.A.A., Ahmed, S.A. (2006) A Novel Hg(II) PVC Membrane Sensor Based on Simple Ionophore Ethylenediamine Bis-Thiophenecarboxaldehyde. Analytical Letters, 39(4): 659-673
Saleh, M.B., Gaber, A.A., Khalaf, M.M.R., Tawfeek, A.M. (2006) Novel Sm(III) Ion-Selective Polymeric Membrane Sensor Based on Spiro[Oxirane-Pyrazolidinedione] Derivative Ionophore. Analytical Letters, 39(1): 17-31
Shokrollahi, A., Ghaedi, M., Montazerozohori, M., Hosaini, O., Ghaedi, H. (2007) Construction of Suitable Iodide Selective Electrode Based on Phenyl Mercury (II)(2 mercaptobezothiozolate) Carrier. Analytical Letters, 40(9): 1714-1735
Singh, A.K., Gupta, V.K., Gupta, B. (2007) Chromium(III) selective membrane sensors based on Schiff bases as chelating ionophores. Analytica chimica acta, 585(1): 171-8
Umezawa, Y., Umezawa, K., Sato, H. (1995) Selectivity coefficients for ion-selective electrodes: Recommended methods for reporting KA,Bpot values (Technical Report). Pure and Applied Chemistry, 67(3): 507-518
Zamani, H., Ganjali, M., Norouzi, P., Adib, M. (2008) Strontium PVC-membrane sensor based on 2-[(2-mercaptophenylimino)methyl]phenol. Materials Science and Engineering: C, 28(1): 157-163
Zamani, H., Ganjali, M., Norouzi, P., Tadjarodi, A., Shahsavani, E. (2008) Materials Science and Engineering: C, 28(8): 1489-1494
Zamani, H., Hamedmosavian, M., Hamidfar, E., Ganjali, M., Norouzi, P. (2008) A novel iron (III)-PVC membrane potentiomeric sensor based on N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid. Materials Science and Engineering: C, 28(8): 1551-1555
Zamani, H.A., Abedini-Torghabeh, J., Ganjali, M.R. (2006) A Highly Selective and Sensitive Barium(II)-Selective PVC Membrane Based on Dimethyl 1-Acetyl-8-oxo-2,8-dihydro- 1H-pyra-zolo[5,1-a]isoindole-2,3-dicarboxylate. Electroanalysis, 18(9): 888-893
Zamani, H.A., Hamed-Mosavian, M.T., Aminzadeh, E., Ganjali, M.R., Ghaemy, M., Behmadi, H., Faridbod, F. (2010) Construction of barium (II) PVC membrane electrochemical sensor based on 3-deoxy-d-erythro-hexos-2-ulose bis (thiosemicarbazone) as a novel ionophore. Desalination, 250(1): 56-61
Zamani, H.A., Ganjali, M.R., Norouzi, P., Adib, M. (2007) Cobalt(II) Ion Detection in Electroplating Wastewater by a New Cobalt Ion-Selective Electrode Based on N-[1-(2-thienyl)ethylidene]-2-furohydrazide. Sensor Letters, 5(3): 522-527
Zamani, H.A., Masrournia, M., Rostame-Faroge, M., Ganjali, M.R., Behmadi, H. (2008) Construction of Nickel (II) PVC Membrane Electrochemical Sensor Based on 5-Methoxy-5,6-Diphenyl-4,5 Dihydro-3(2H)-Pyridazinethione as a Novel Ionophore. Sensor Letters, 6(5): 759-764
Zamani, H.A., Rajabzadeh, G., Ganjali, M.R. (2006) Highly selective and sensitive chromium(III) membrane sensors based on 4-amino-3-hydrazino-6-methyl-1,2,4-triazin-5-one as a new neutral ionophore. Sensors and Actuators B: Chemical, 119(1): 41-46
Zamani, H.A., Rajabzadeh, G., Masrornia, M., Dejbord, A., Ganjali, M.R., Seifi, N. (2009) Determination of Cr3+ ions in biological and environmental samples by a chromium(III) membrane sensor based on 5-amino-1-phenyl-1H-pyrazole-4-carboxamide. Desalination, 249(2): 560-565
Zamani, H.A., Ganjali, M.R., Salavati-Niasari, M. (2008) Fabrication of an iron(III)-selective PVC membrane sensor based on a bis-bidentate Schiff base ionophore. Transition Metal Chemistry, 33(8): 995-1001
Zamani, H.A., Rohani, M., Zangeneh-Asadabadi, A., Saleh, Z.M., Ganjali, M.R., Salavati-Niasari, M. (2010) A novel lutetium(III) PVC membrane sensor based on a new symmetric S-N Schiff's base for Lu(III) analysis in real sample. Materials Science and Engineering: C, 30(6): 917-920