|
|
|
|
Facta universitatis - series: Physics, Chemistry and Technology 2007, vol. 5, br. 1, str. 61-67
|
|
|
Proizvodnja biodizela iz žutih masnoća sa slobodnim masnim kiselinama
Faculte des Sciences & Techniques, Departement de genie chimique, Tanger, Maroc
SažetakBiodizel je ekološko gorivo dobijeno preradom biljnih i životinjskih masti recikliranih za kuhinjsku upotrebu (žute masnoće). Ove žute masnoće sadrže velike količine slobodnih masnih kiselina koje, u prisustvu alkalnih katalizatora, formiraju sapune. Da bi se formiranje sapuna izbeglo neophodan je pred-postupak tretiranja sirovog materijala kiselim katalizatorima. Reakcija transesterifikacije je kompletna u prisustvu alkalnih katalizatora. Najveća proizvodnja biodizela odgovara molarnom protoku od 4.985 kmol.hr-1 metil oleata i 4.658 kmol.hr-1 metil butirata.
Ključne reči
|
|
|
|
Reference
|
|
|
*** (1997) The Kyoto protocol to United Nation Framework convention on climate change. Kyoto
|
|
|
Agence de l'Environnement et de la Maitrise de l'Energie (2006) Changement Climatique: Un défi majeur. http://www. ademe. fr
|
|
|
Aracil, J. (2003) Produccion de biodiesel a partir de aceites usados Laboratorio de Procesos Químicos y Bioquímicos Integrados. Madrid: Universidad Complutense, www.sodean.es/documentos/jornadabiodiesel
|
|
 3
|
Canakci, M., van Gerpen, J. (2001) Biodiesel production from oils and fats with high free fatty acids. Transactions of the ASAE, 44(6), 1429-1436
|
|
3
|
Canakci, M., van Gerpen, J. (1999) Biodiesel production via acid catalysis. Transactions of the ASAE, 42(5), 1203-1210
|
|
|
ETSIA Grazas Y.Aceites (2006) Internal report. Escuela Técnica Superior de Ingenieros Agrónomos de Madrid, www.etsia.upm.es/fedna/grasasyaceites/grasa_mezcla.htm
|
|
|
Fisher, E.M., Pitz, W.J., Curran, H.J., Westbrook, C.K. (2000) Detailed chemical kinetic mechanisms for combustion of oxygenated fuels. Proceedings of the Combustion Institute, 28(Pt. 2), 1579-1586
|
|
|
Formo, M. (1954) Ester reactions of fatty materials. Journal of the American Oil Chemists Society, 31(11): 548
|
|
|
Pestes, M.N., Stanislao, J. (1984) Piston ring deposits when using vegetable oil as a fuel. Journal of Testing and Evaluation, 12(2), 61-8
|
|
|
Romano, S. (1984) Vegetables oils: A new alternative. u: Proceedings Of The International Conference On Plant And Vegetables Oils As Fuels 10-116, Fargo, 2-4 Agust, St. Joseph, Michigan: ASAE
|
|
2
|
Schuchardt, U., Serchelia, R., Matheus, M. (1998) Transesterification of vegetable oils: Review. J Braz Chem Soc, 9 (1), 199-210
|
|
|
Strong, C., Erickson, C., Shukla, D. (2004) Evaluation of biodiesel fuel: Literature review. Bozeman: Western Transportation Institute, College of Engineering, Montana State University
|
|
4
|
van Gerpen, J., Shanks, B., Pruszko, R., Clements, D., Knothe, G. (2004) Biodiesel production technology. National Renewable Energy Laboratory, Contract br. DE-AC36-99-GO10337
|
|
|
Zhang, Q., Feldman, M., Peterson, C. (1988) Diesel engine durability when fuelled with methyl ester of winter rapessed oil. ASAE Paper, St. Joseph Mich, br. 88-1562
|
|
|
|
|