članak: 1 od 1  
Hemijska industrija
2011, vol. 65, br. 2, str. 103-114
jezik rada: srpski
pregledni članak
doi:10.2298/HEMIND100913068S

Novi trendovi u proizvodnji bioetanola
aUniverzitet u Beogradu, Tehnološko-metalurški fakultet
bTehnološko-metalurški fakultet, Beograd + Hemofarm A.D., Vršac
cEvropski univerzitet, Beograd, Fakultet za internacionalni menadžment

e-adresa: lmojovic@tmf.bg.ac.rs

Sažetak

Bioetanol je biogorivo koje se širom sveta koristi kao zamena za fosilna goriva. Upotrebom smeša bioetanola i benzina može se znatno smanjiti potreba za naftom kao i emisija gasova staklene bašte, odnosno zagađenje životne sredine. Iako se bioetanol već decenijama proizvodi iz skrobnih i šećernih sirovina, useva namenjenih prvenstveno ishrani, danas se smatra da korišćenje obradivih poljoprivrednih površina za proizvodnju ovog goriva nije opravdano pa se intenzivno razvijaju tehnologije za njegovo dobijanje iz lignoceluloznih izvora biomase kao što su šumski, poljoprivredni i komunalni otpad. Upotreba lignocelulozne biomase za proizvodnju biogoriva biće neizbežna u bližoj budućnosti kada se očekuje da će se tečna fosilna goriva morati zameniti obnovljivim održivim alternativama. Primena novih enzimskih sistema za hidrolizu celuloze, sinteza fermentativnih sojeva tolerantnih na inhibitore koji fermentišu pentozu, u kombinaciji sa optimizovanom integracijom procesa, obećavaju značajan napredak.

Ključne reči

Reference

*** (2008) Program modernizacije Rafinerije nafte biznis plan. Pančevo: NIS
*** (2009) Draft decision-/CP. 15, United Nations Framework Convention on Climate Change. Copenhagen, http://unfccc.int/resource/docs/2009/cop15/eng/l07.pdf
*** (2008) Renewable energy network for the 21st century (REN21), renewable 2007 global status report. Paris: REN21 Secretariat
Badger, P.C. (2002) Ethanol from cellulose: A general review. u: Janick J., Whipkey A. (ur.) Trends in new crops and new uses, Alexandria: ASHS Press
Balat, M., Balat, H. (2009) Recent trends in global production and utilization of bio-ethanol fuel. Applied Energy, 86(11): 2273
Ballesteros, I., Oliva, J., Negro, M., Manzanares, P., Ballesteros, M. (2002) Enzymic hydrolysis of steam exploded herbaceous agricultural waste (Brassica carinata) at different particule sizes. Process Biochemistry, 38(2): 187-192
Bayer, E.A., Lamed, R., Himmel, M.E. (2007) The potential of cellulases and cellulosomes for cellulosic waste management. Current Opinion in Biotechnology, 18(3): 237-245
Berlin, A., Gilkes, N., Kilburn, D., Bura, R., Markov, A., Skomarovsky, A., Okunev, O., Gusakov, A., Maximenko, V., Gregg, D., Sinitsyn, A., Saddler, J. (2005) Evaluation of novel fungal cellulase preparations for ability to hydrolyze softwood substrates: Evidence for the role of accessory enzymes. Enzyme and Microbial Technology, 37(2): 175-184
Cardona, C.A., Sanchez, O.J. (2007) Fuel ethanol production: Process design trends and integration opportunities. Bioresource Technology, 98(12): 2415
Christensen, K., Smith, A. (2008) The case for hemp as biofuel. Brattleboro: Vote Hemp Inc, Report
Christy, S., Warren, S. (2005) Market study on projected oil demand in Serbia and Montenegro and regional trade. London: Petroleum Economics Limited
Claassen, P.A.M., van Lier, J.B., Lopez, C.A.M., van Niel, E.W.J., Sijtsma, L., Stams, A.J.M., de Vries, S.S., Weusthuis, R.A. (1999) Utilisation of biomass for the supply of energy carriers. Applied Microbiology and Biotechnology, 52(6): 741-755
de Fraiture, C., Giordano, M., Liao, Y. (2008) Biofuels and implications for agricultural water use: Blue impacts of green energy. Water Policy, 1 (10) 67-80
Demirbas, A. (2005) Bioethanol from cellulosic materials: A renewable motor fuel from biomass. Energy Sources, 27(4): 327
Demirbas, A. (2007) Producing and Using Bioethanol as an Automotive Fuel. Energy Sources, Part B: Economics, Planning, and Policy, 2(4): 391-401
Furman, T., Nikolić, R., Brkić, M., Kovčin, S., Crnobarac, J., Jovanović, M., Tomić, M., Savin, L., Skala, D., Klinar, I., Marinković, R., Radovanović, M., Petrović, S., Marić, M., Tomić, D., Ocić, O., i dr. (2005) Biodizel - alternativno i ekološko tečno gorivo. Novi Sad: Poljoprivredni fakultet - Departman za poljoprivrednu tehniku
Ghosh, P., Ghose, T.K. (2003) Bioethanol in India: Recent past and emerging future. Adv. Bioch. Eng. Biot, 85, str. 1-27
Hamelinck, C., Hooijdonk, G., Faaij, P.C.A. (2005) Ethanol from lignocellulosic biomass: Techno - economic performance in short-, middle-, and long- term. Biomass and Bioenergy, 28(4): 384
Katahira, S., Mizuike, A., Fukuda, H., Kondo, A. (2006) Ethanol fermentation from lignocellulosic hydrolysate by a recombinant xylose- and cellooligosaccharide-assimilating yeast strain. Applied Microbiology and Biotechnology, 72(6): 1136-1143
Kojima, M., Johnson, T. (2005) Potential for biofuels for transport in developing countries. Washington, Energy sector management assistance programme, joint UNDP/World Bank
Laser, M., Schulman, D., Allen, S.G., Lichwa, J., Antal, M.J., Lynd, L.R. (2002) A comparison of liquid hot water and steam pretreatments of sugar cane bagasse for bioconversion to ethanol. Bioresource Technology, 81(1): 33-44
Li, W., Xu, J., Wang, J., Yan, Y., Zhu, X., Chen, M., Tan, Z. (2008) Studies of Monosaccharide Production through Lignocellulosic Waste Hydrolysis Using Double Acids. Energy & Fuels, 22(3): 2015-2021
Lynd, L.R. (1996) Overview and evaluation of fuel ethanol from cellulosic biomass: technology, Economics, the Environment, and Policy. Annual Review of Energy and the Environment, 21(1): 403-465
Lynd, L.R., Weimer, P.J., Zyl, W.H., Pretorius, I.S. (2002) Microbial cellulose utilization: Fundamentals and biotechnology. Microbiol Mol Biol Rev, 66(3): 506-77, table of contents
Margeot, A., Hahn-Hagerdal, B., Edlund, M., Slade, R., Monot, F. (2009) New improvements for lignocellulosic ethanol. Current Opinion in Biotechnology, 20(3): 372-380
Mitchell, D. (2008) A note on rising food prices. Washington: World Bank Development Prospects Group, World Bank
Mojović, Lj., Nikolić, S., Rakin, M., Vukašinović, M. (2006) Production of bioethanol from corn meal hydrolyzates. Fuel, vol. 85, br. 12-13, str. 1750-1755
Mojović, L., Pejin, D., Lazić, M. (2007) Bioetanol kao gorivo - stanje i perspektive. Leskovac: Tehnološki fakultet
Mojović, L., Pejin, D., Grujić, O., Markov, S., Pejin, J., Rakin, M., Vukašinović, M., Nikolić, S., Savić, D. (2009) Progress in the production of bioethanol on starch-based feedstocks. Chemical Industry and Chemical Engineering Quarterly / CICEQ, vol. 15, br. 4, str. 211-226
Negro, M.J., Manzanares, P., Ballesteros, I., Oliva, J.M., Cabanas, A., Ballesteros, M. (2003) Hydrothermal pretreatment conditions to enhance ethanol production from poplar biomass. Applied Biochemistry and Biotechnology, 105(1-3): 87-100
Nikolic, S., Mojovic, L.V., Rakin, M.B., Pejin, D.J., Pejin, J. (2010) Ultrasound-assisted production of bioethanol by simultaneous saccharification and fermentation of corn meal. Food Chemistry, vol. 122, br. 1, str. 216-222
Nikolic, S., Mojovic, L.V., Rakin, M.B., Pejin, D.J. (2009) Bioethanol production from corn meal by simultaneous enzymatic saccharification and fermentation with immobilized cells of Saccharomyces cerevisiae var. ellipsoideus. Fuel, vol. 88, br. 9, str. 1602-1607
Nikolic, S., Mojovic, L.V., Pejin, D.J., Rakin, M.B., Vucurovic, V. (2009) Improvement of Ethanol Fermentation of Corn Semolina Hydrolyzates with Immobilized Yeast by Medium Supplementation. Food Technol. Biotechnol, vol. 47, br. 1, str. 83-89
Ocić, O. (2005) Oil refineries in the 21st century. Wiley, monograph
Ogier, J.C., Leygue, J.P., Ballerini, D., Pourquie, J., Rigal, L. (1999) Production d'ethanol a partir de biomasse lignocellulosique. Oil & Gas Science and Technology, 54(1): 67-94
Ojumu, T.V., Ogunkunle, O.A. (2005) Production of glucose from lignocellulosic under extremely low acid and high temperature in batch process, auto-hydrolysis approach. J. Appl. Sci, 5(1), 15-17
Palonen, H., Viikari, L. (2004) Role of oxidative enzymatic treatments on enzymatic hydrolysis of softwood. Biotechnol. Bioeng, 86, str. 550-557
Predojević, Z.J. (2010) Postupci pripreme lignocelulozne sirovine za dobijanje bioetanola. Hemijska industrija, vol. 64, br. 4, str. 283-293
Sanchez, O.J., Cardona, C.A. (2008) Trends in biotechnological production of fuel ethanol from different feedstocks. Bioresource Technology, 99(13): 5270
Semenčenko, D., Radosavljević, M., Semenčenko, V. (2009) Uloga i mesto istraživanja i primene biogoriva u strategijama razvoja obnovljivih izvora energije. u: Simpozijum o operacionim istraživanjima (XXXVI), Sym-op-is, Ivanjica
Shahbazi, A., Li, Y., Mims, M.R. (2005) Application of sequential aqueous steam treatments to the fractination of softwood. Appl. Biochem. Biotech, 26, str. 973-987
Smith, A.M. (2008) Prospects for increasing starch and sucrose yields for bioethanol production. Plant Journal, 54(4): 546-558
Soderstrom, J., Pilcher, L., Galbe, M., Zacchi, G. (2003) Two-step steam pretreatment of softwood by dilute H2SO4 impregnation for ethanol production. Biomass and Bioenergy, 24(6): 475-486
Sues, A., Millati, R., Edebo, L., Taherzadeh, M. (2005) Ethanol production from hexoses, pentoses, and dilute-acid hydrolyzate by. FEMS Yeast Research, 5(6-7): 669-676
Sun, Y., Cheng, J. (2002) Hydrolysis of lignocellulosic materials for ethanol production: a review. Bioresource Technology, 83(1): 1
Tasić, M.B., Banković-Ilić, I.B., Lazić, M.L., Veljković, V.B., Mojović, L.V. (2006) Bioetanol - stanje i perspektive. Hemijska industrija, vol. 60, br. 1-2, str. 1-9
Xu, Q., Singh, A., Himmel, M.E. (2009) Perspectives and new directions for the production of bioethanol using consolidated bioprocessing of lignocellulose. Current Opinion in Biotechnology, 20(3): 364-371
Yoosin, S., Sorapipatana, C. (2007) A study of ethanol production cost for gasoline substitution in Thailand and its competitiveness. Thammasat Int. J. Sci. Technol, 12, str. 69-80
Zhang, B.S. (2006) Process for preparing fuel ethanol by using straw fiber materials. Patent CN1880416
Zhang, Y.P., Lynd, L.R. (2004) Toward an aggregated understanding of enzymatic hydrolysis of cellulose: noncomplexed cellulase systems. Biotechnology and bioengineering, 88(7): 797-824