Metrika članka

  • citati u SCindeksu: [5]
  • citati u Google Scholaru:[=>]
  • posete u prethodnih 30 dana:8
  • preuzimanja u prethodnih 30 dana:0
članak: 1 od 1  
Chemical Industry and Chemical Engineering Quarterly / CICEQ
2009, vol. 15, br. 4, str. 237-249
jezik rada: engleski
vrsta rada: naučni članak
doi:10.2298/CICEQ0904237S


Heavy metal ions adsorption from mine waters by sawdust
(naslov ne postoji na srpskom)
Univerzitet u Beogradu, Tehnički fakultet u Boru

e-adresa: vstankovic@tf.bor.ac.rs

Projekat

Projekat Ministarstva nauke Republike Srbije, br. 142014B i 21008

Sažetak

(ne postoji na srpskom)
In this work the results on the batch and column adsorption of copper and some associated ions by employing linden and poplar sawdust as a low-cost adsorbent are presented. The mine water from a local abandoned copper mine, as well as synthetic solutions of those ions which are the main constituents of the mine water were both used as a model-system in this study. The adsorption ability of the chosen sawdust to adsorb heavy metal ions is considered as a function of the initial pH of the solution and kind of metal ions. At lower pH of solutions the adsorption percentage (AD %) decreases leading to a zero AD % at pH < 1.1. Maximum AD % is achieved at 3.5 < pH < 5. It was found that poplar and linden sawdust have both almost equal adsorption capacities against copper ions. The highest AD % ( ?80%) was achieved for Cu2+, while for Fe2+ it was slightly above 10%. The other considered ions (Zn2+ and Mn2+) were within this interval. The results obtained in the batch mode were verified through the column test by using the real mine water originating from an acid mine drainage (AMD) of the copper mine 'Cerovo', RTB Bor. The breakthrough curves are presented as a function of the aqueous phase volume passed through the column allowing having an insight into the column adsorption features. Breakthrough points were determined for copper, manganese and zinc ions. A very high adsorption degree - higher than 99% was achieved in these experiments for all mentioned ions. After completing the adsorption, instead of desorption, the loaded sawdust was drained, dried and burned; the copper bearing ash was then leached with a controlled volume of sulphuric acid solution to concentrate copper therein. The obtained leach solution had the concentration of copper higher than 15 g dm-3 and the amount of H2SO4 high enough to serve as a supporting electrolyte suitable to be treated by the electrowinning for recovery of copper. The technology process based on the column adsorption is proposed and discussed.

Ključne reči

Reference

*** (2005) The report on mining for closure. UNEP
Acar, F.N., Eren, Z. (2006) Removal of Cu(II) ions by activated poplar sawdust (Samsun Clone) from aqueous solutions. Journal of Hazardous Materials, 137(2): 909
Ajmal, M., Khan, A.H., Ahmad, S., Ahmad, A. (1998) Role of sawdust in the removal of copper(II) from industrial wastes. Water Res, 32, 10, 3085-3091
Aksu, Z., Göneu, F. (2004) Biosorption of phenol by immobilized activated sludge in a continuous packed bed: prediction of breakthrough curves. Process Biochemistry, 39(5): 599
Argun, M.E., Dursun, S. (2008) A new approach to modification of natural adsorbent for heavy metal adsorption. Bioresource Technology, 99(7): 2516
Bailey, S.E., Olin, T.J., Bricka, R.M., Adrian, D.D. (1999) A review of potentially low-cost sorbents for heavy metals. Water Res, 33, str. 2469-2479
Basso, M.C., Cerrella, E.G., Cukierman, A.L. (2002) Lignocellulosic materials as potential biosorbents of trace toxic metals from wastewater. Industrial & Engineering Chemistry Research, 41(15): 3580
Boddu, V.M., Abburi, K., Talbott, J.L., Smith, E.D. (2003) Removal of hexavalent chromium from wastewater using a new composite chitosan biosorbent. Environ Sci Technol, 37(19): 4449-56
Bozic, D., Stankovic, V.D., Gorgievski, M., Bogdanovic, G.D., Kovacevic, R. (2009) Adsorption of heavy metal ions by sawdust of deciduous trees
Chartr, M.M.G., Bunce, N.J. (2003) Journal of Applied Electrochemistry, 33(3/4): 259
Dupont, L., Bonauda, J., Dumoucean, J., Aplincourt, M. (2005) Biosorption of Cu(II) and Zn(II) onto a lignocellulosic substrate extracted from wheat bran. Environmental Chemistry Letters, 2(4): 165
Febrianto, J., Kosasih, A.N., Sunarso, J., Ju, Y., Indraswati, N., Ismadji, S. (2009) Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: A summary of recent studies. Journal of Hazardous Materials, 162(2-3): 616
Fiol, N., Villaescusa, I., Martinez, M., Miralles, N., Poch, J., Serarols, J. (2006) Sorption of Pb(II), Ni(II), Cu(II) and Cd(II) from aqueous solution by olive stone waste. Separation and Purification Technology, 50(1): 132
Gaballah, I., Goy, D., Kilbertus, G., Thauront, J. (1994) Decontamination of industrial effluents for environment protection and recycling of metals. Resources Conservation and Recycling, 10(1-2): 97
Gaballah, I., Kilbertus, G. (1998) Recovery of heavy metal ions through decontamination of synthetic solutions and industrial effluents using modified barks. Journal of Geochemical Exploration, 62(1-3): 241
Gorgievski, M., Bozic, D., Stankovic, V.D., Bogdanovic, G.D. (2009) Copper electrowinning from acid mine drainage: A case study from the closed mine 'Cerovo'
Grupa autora (2002) Assessment of environmental monitoring capacities Bor: Mission report. u: Interagency Mission to Bor, 13-17 May
Gupta, S., Babu, B.V. (2009) Removal of toxic metal Cr(VI) from aqueous solutions using sawdust as adsorbent: Equilibrium, kinetics and regeneration studies. Chem. Eng. J, Volume 150, Issues 2-3, 352-365
Habashi, F. (1997) Handbook of extractive metallurgy. Berlin: Wiley-VCH, vol. 4
Ho, Y., Chiu, W., Hsu, C., Huang, C. (2004) Sorption of lead ions from aqueous solution using tree fern as a sorbent. Hydrometallurgy, 73(1-2): 55
Ho, Y.S., Mckay, G. (1999) Institution of chemical engineers trans. IChem E., vol. 77, Part B, May
Ho, Y.S., Mckay, G. (2000) The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Water Research, 34(3): 735
Ishikawa, S., Suyama, K., Arihara, K., Itoh, M. (2002) Uptake and recovery of gold ions from electroplating wastes using eggshell membrane. Bioresour Technol, 81(3): 201-6
Jang, L.K., Nguyen, D., Geesey, G.G. (1995) Effect of pH on the absorption of Cu(II) by alginate gel. Water Research, 29(1): 315
Jüttner, K., Galla, U., Schmieder, H. (2000) Electrochemical approaches to environmental problems in the process industry. Electrochimica Acta, 45(15-16): 2575
Larous, S., Meniai, A., Lehocine, M.B. (2005) Experimental study of the removal of copper from aqueous solutions by adsorption using sawdust. Desalination, 185(1-3): 483
Lu, D., Cao, Q., Li, X., Cao, X., Cao, F., Shao, W. (2009) Kinetics and equilibrium of Cu(II) adsorption onto chemically modified orange peel cellulose biosorbents. Hydrometallurgy, 95(1-2): 145
Lu, S., Gibb, S.W. (2008) Copper removal from wastewater using spent-grain as biosorbent. Bioresource Technology, 99(6): 1509
Mohan, D., Pittman, C.U.Jr. (2007) Arsenic removal from water/wastewater using adsorbents: A critical review. Journal of Hazardous Materials, 142(1-2): 1
Mohan, S., Sreelakshumi, G. (2008) Fixed bed column study for heavy metal removal using phosphate treated rice husk. Journal of Hazardous Materials, 153(1-2): 75
Ngah, W.S.W., Hanafiah, M.A.K.M. (2008) Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: A review. Bioresource Technology, 99(10): 3935
Pérez-López, R., Miguel, N.J., Ruiz, de A.G. (2007) Immobilization of toxic elements in mine residues derived from mining activities in the Iberian Pyrite Belt (SW Spain): Laboratory experiments. Applied Geochemistry, 22(9): 1919
Rodriguez-Cruz, S., Andrades, M.S., Sanchez-Camazano, M., Sanchez-Marth, M.J. (2007) Relationship between the adsorption capacity of pesticides by wood residues and the properties of woods and pesticides. Environmental Science & Technology, 41(10): 3613
Schiewer, S., Volesky, B. (1997) Ionic strength and electrostatic effects in biosorption of protons. Environmental Science & Technology, 31(7): 1863
Schiewer, S., Volesky, B. (1997) Ionic strength and electrostatic effects in biosorption of divalent metal ions and protons. Environmental Science & Technology, 31(9): 2478
Schiewer, S., Volesky, B. (1995) Modeling of the proton-metal ion exchange in biosorption. Environmental Science & Technology, 29(12): 3049
Shukla, A., Zhang, Y., Dubey, P., Margrave, J.L., Shukla, S.S. (2002) The role of sawdust in the removal of unwanted materials from water. J Hazard Mater, 95(1-2): 137-52
Shukla, S.S., Yu, L.J., Dorris, K.L., Shukla, A. (2005) Removal of nickel from aqueous solutions by sawdust. J Hazard Mater, 121(1-3): 243-6
Srinivasa, R.P., Reddy, K.V.N.S., Kalyar, S., Krishuciah, A. (2007) Comparative sorption of copper and nickel from aqueous solutions by natural neem (Azadirachta indica) sawdust and acid treated sawdust. Wood Science and Technology, 41(5): 427
Stankovic, V. (2007) Metal removal from effluents by electrowinning and a new design concept in wastewater purification technology. Chemical and Biochemical Engineering Quarterly, 21(1): 33-45
Šćiban, M.B., Radetic, Bogdanka., Kevresan, Žarko., Klasnja, Mile. (2007) Adsorption of heavy metals from electroplating wastewater by wood sawdust
Šćiban, M.B., Klasnja, M., Skrbic, B. (2006) Modified softwood sawdust as adsorbent of heavy metal ions from water
Taty-Christian, V., Fauduet, H., Porte, C., Delacroix, A. (2003) Removal of Cd(II) and Pb(II) ions, from aqueous solutions, by adsorption onto sawdust of Pinus sylvestris. J Hazard Mater, 105(1-3): 121-42
Taty-Costodes, V.C., Fauduet, H., Porte, C., Ho, Y.S. (2005) Removal of lead (II) ions from synthetic and real effluents using immobilized sawdust: Adsorption on a fixed-bed column. Journal of Hazardous Materials, 123(1-3): 135
Tofan, L., Paduraru, C., Bilbia, D., Rotoriu, M. (2008) Thermal power plants ash as sorbent for the removal of Cu(II) and Zn(II) ions from wastewaters. Journal of Hazardous Materials, 156(1-3): 1
Unnitham, M.R., Anirudham, T.S. (2001) The Kinetics and Thermodynamics of Sorption of Chromium(VI) onto the Iron(III) Complex of a Carboxylated Polyacrylamide-Grafted Sawdust. Industrial & Engineering Chemistry Research, 40(12): 2693
Villaescusa, I., Fiol, N., Martínez, M., Miralles, N., Poch, J., Serarols, J. (2004) Removal of copper and nickel ions from aqueous solutions by grape stalks wastes. Water Res, 38(4): 992-1002
Volesky, B., Holan, Z.R. (1995) Biosorption of heavy metals. Biotechnol Prog, 11(3): 235-50
Yasemin, B., Zeki, T. (2007) Removal of heavy metals from aqueous solution by sawdust adsorption. Journal of Environmental Sciences, 19(2): 160
Yu, B., Zhang, Y., Shukla, A., Shukla, S.S., Dorris, K.L. (2000) The removal of heavy metal from aqueous solutions by sawdust adsorption: Removal of copper. J Hazard Mater, 80(1-3): 33-42
Yu, B., Zhang, Y., Shukla, A., Shukla, S.S., Dorris, K.L. (2001) The removal of heavy metals from aqueous solutions by sawdust adsorption: Removal of lead and comparison of its adsorption with copper. J Hazard Mater, 84(1): 83-94