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2022, vol. 63, br. 4, str. 454-462
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Inhibicija korozije cevovoda od legure L 80, koji nosi simuliranu vodu iz bunara, ćilibarnom kiselinom
Inhibition of corrosion of L 80 alloy pipeline carrying simulated oil well water by succinic acid
Krishnaveni Arjunana, Anitha Nilavanb, Velkannan Veerapandianc, Jayanthi Sampathkumard, Shanthi Thangaiyane, Sevvanthi Kuttipaiyand, Kaniya Duraisamyd, Thulasi Elumalaid, Sarmina Duraisamyd, Singh Gurmeetf, Al-Hashem Abdulhameedg, Rajendran Susaih, Lačnjevac Časlavi
aYadava College, Department of Chemistry, Madurai, India + Madurai Kamaraj University, Madurai, India bSt. Antony's College of Arts and Sciences for Women, Department of Chemistry, Corrosion Research Centre, Dindigul, India cThiagarajar College of Engineering, Department of Chemistry, Thiruparankundram, Madurai, Tamil Nadu, India dNamakkal Kavignar Ramalingam Government Arts College for Women, Department of Chemistry, Namakkal, India eArasu College of Arts and Sciences for Women, Department of Chemistry, Karur, India fPondicherry University, Puducherry, India gKuwait Institute for Scientific Research, Petroleum Research Centre, Kuwait City, Kuwait hSt. Antony's College of Arts and Sciences for Women, Department of Chemistry, Corrosion Research Centre, Dindigul, India + Pondicherry University, Centre for Nanoscience and Technology, Puducherry, India iUniverzitet u Beogradu, Poljoprivredni fakultet, Srbija
e-adresa: susairajendran@gmail.com
Sažetak
Voda iz naftne bušotine (SOWW) ispušta se cevovodima napravljenim od nekoliko legura, na primer mekog čelika L80. Ove legure mogu, ispuštajući vodu iz naftnih bunara, da podležu koroziji zbog prisustva različitih agresivnih jona prisutnih u vodi iz naftne bušotine (SOWW). Da bi se ovo sprečilo, korišćeno je nekoliko inhibitora. Inhibicija korozije cevovoda od legure L80, koji nosi simuliranu vodu iz bunara, ćilibarnom kiselinom je procenjena elektrohemijskim studijama kao što su studija polarizacije i spektri AC impedanse (EIS). Studija polarizacije otkriva da u prisustvu inhibitora raste otpor linearne polarizacije, a struja korozije opada. Spektri impedanse naizmenične struje otkrivaju da u prisustvu ćilibarne kiseline, vrednost RT raste, vrednost impedanse raste, fazni ugao raste i vrednost Cdl opada. Ova studija otkriva da kada se ćilibarna kiselina doda simuliranoj vodi iz naftnih bunara, otpornost legure L80 na koroziju se povećava. To implicira da se ćilibarna kiselina može dodati simuliranoj vodi iz naftnih bunara koja teče kroz cevovod od legure L80.
Abstract
Simulated oil well water (SOWW) is conceded out by pipelines made of several alloys, for instance mild steel L80. These alloys may simulated oil well water undergo corrosion owing to presence of various aggressive ions present in SOWW. To prevent this several inhibitors have been used. Inhibition of corrosion of L80 alloy pipeline carrying simulated oil well water by succinic acid has been evaluated by electrochemical studies such as polarization study and AC impedance spectra (EIS). Polarisation study reveals that in the presence of inhibitor linear polarization resistance increases and corrosion current decreases. AC impedance spectra reveal that in presence of succinic acid, RT value increases, impedance value increases, phase angle increases and Cdl value decreases. The present study reveals that when succinic acid is added to simulated oil well water, the corrosion resistance of L80 alloy increases. It implies that succinic acid may be added to simulated oil well water flowing through pipe line made of L80 alloy.
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