Inhibition of corrosion of mild steel hull plates immersed in natural sea water by sandalwood oil extract of some natural products

Rajendran, Dorothy; Sasilatha, Thankappan; Santhammal, Rajendran Susai; Al-Hashem, Abdulhameed; Lačnjevac, Časlav; Singh, Gurmeet

doi:10.5937/zasmat2201023R

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Zaštita materijala

2022, vol. 63, br. 1, str. 23-36

Sprečavanje korozije ploča od mekog čelika potopljenih u morsku vodu ekstraktom ulja nekih prirodnih proizvoda

Rajendran Dorothy^a, Sasilatha Thankappan^a, Santhammal Rajendran Susai^b, Al-Hashem Abdulhameed^c, Lačnjevac Časlav^d, Singh Gurmeet^e

^aAMET University, Department of EEE, Chennai, India
^bSt. Antony's College of Arts and Sciences for Women, Department of Chemistry, Tamil Nadu, India + Pondicherry University, Puducherry, India
^cKuwait Institute for Scientific Research, Petroleum Research Centre, Kuwait
^dUniverzitet u Beogradu, Poljoprivredni fakultet, Srbija
^ePondicherry University, Puducherry, India

e-adresa: susairajendran@gmail.com

Ključne reči: inhibicija korozije; ploče trupa; meki čelik; morska voda; zeleni inhibitori; elektrohemijska studija

Sažetak

Ploče trupa broda od mekog čelika (MČ) su uvek u kontaktu sa morskom vodom i uvek su u kontaktu sa agresivnim jonima, kao što su hlorični joni prisutni u morskoj vodi. Otpornost na koroziju ploča trupa broda od mekog čelika je istražen proučavanjem polarizacije. Ekstrakt ulja sandalovine, koji sadrži po 5 g kardamoma, karanfilića, muskatnog oraščića, Indija Sambrani (loban), Chrysopogon zizanioides, poznatijeg kao vetiver i kamfor, korišen je kao inhibitor korozije zajedno sa trinatrijum citratom, natrijum dihidrogenom fosfat i Zn2+. Otpornost na koroziju je merena u odsustvu i prisustvu različitih inhibitornih sistema: Trinatrijum citrat (TSC) 100 ppm+ Zn2+ 50 ppm sistem, natrijum dihidrogen fosfat (SDP) 100 ppm+ Zn2+ 50 ppm sistem, obložen uljem (3 dana) MČ, uljem premazan (3 dana) MČ +TSC 100 ppm+ sistem obložen ZN2+ 5 ppm+ sistem MS +SDP100 ppm+ Zn2+ 50 ppm. Primećeno je da kada je meki čelik uronjen u sistem SV+TSC 100 ppm + Zn2+ 50ppm, otpornost MČ na koroziju se povećava. Kada je meki čelik uronjen u sistem SV+ SDP 100 ppm + Zn2+ 50 ppm, otpornost MČ na koroziju se povećava Kada se meki čelik uroni u MS obložen uljem (3 ana) u sistem morske vode, otpornost MČ na koroziju se povećava. Kada se meki čelik uroni u MS obložen uljem (3 dana) u sistem SV+TSC 100 ppm + Zn2+ 50ppm, otpornost MČ na koroziju se povećava. Kada se meki čelik uroni u MS obložen uljem (3 dana) u sistem SV+ SDP 100 ppm + Zn2+ 50 ppm, otpornost MČ na koroziju se povećava. Ovo se ojjašnjava činjenicom da dolazi do povećanja vrednosti LPR i smanjenja vrednosti struje korozije. Potencijal korozije se pomera na anodnu stranu. Ovo ukazuje da se u ovom sistemu inhibitora pretežno kontroliše anodna reakcija rastvaranja metala. Ovo implicira da se ovi sistemi inhibitora mogu obložiti na površinu od mekog čelika koji se koristi kao ploče trupa da bi se sprečila korozi a mekog čelika u morskoj vodi.

Abstract

The hull plates of the ship made of mild steel (MS) are always in contact with seawater are always in contact with aggressive ions such as chloride ions present in seawater.The corrosion resistance of the hull plates of the ship made of mild steel has been investigated by polarization study. Sandalwood oil extract containing 5 g each of Cardamom (disambiguation), Clove (disambiguation), Nutmeg, India Sambrani (loban), Chrysopogon zizanioides, commonly known as vetiver and Camphor was used as corrosion inhibitor along with Trisodium citrate (TSC), sodium dihydrogen phosphate (SDP) and Zn2+. The corrosion resistance was measured in the absence and presence of various inhibitor systems: Trisodium citrate (TSC) 100 ppm+ Zn2+ 50ppm system, sodium dihydrogen phosphate (SDP) 100 ppm+ Zn2+ 50ppm system, Oil coated (3days) MS, Oil coated (3days) MS +TSC 100 ppm+ Zn2+ 50 ppm system and Oil coated (3days) MS +SDP100 ppm+ Zn2+ 50 ppm system were used. It is observed that when mild steel is immersed in SW+TSC 100 ppm+ Zn2+ 50ppm system , the corrosion resistance of MS increases. When mild steel is immersed in SW+ SDP 100 ppm+ Zn2+ 50ppm system , the corrosion resistance of MS increases. When mild steel is immersed in Oil coated (3days) MS in Sea water system , the corrosion resistance of MS increases. When mild steel is immersed in Oil coated (3days) MS in SW+TSC 100 ppm+ Zn2+ 50ppm system , the corrosion resistance of MS increases. When mild steel is immersed in Oil coated (3 days) MS in SW+ SDP 100 ppm+ Zn2+ 50ppm system , the corrosion resistance of MS increases. This is revealed by the fact that there is increase in LPR value and decrease in corrosion current value. The corrosion potential is shifted to anodic side. This indicates that in this inhibitor system, the anodic reaction of metal dissolution is controlled predominantly. This implies that these inhibitor systems may be coated on mild steel surface used as hull plates to prevent corrosion of mild steel in sea water.

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O članku

jezik rada: engleski
vrsta rada: naučni članak
DOI: 10.5937/zasmat2201023R
primljen: 28.08.2021.
revidiran: 22.09.2021.
prihvaćen: 09.10.2021.
objavljen u SCIndeksu: 10.03.2022.

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