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Advanced Technologies
2019, vol. 8, br. 2, str. 46-57
jezik rada: engleski
vrsta rada: izvorni naučni članak
objavljeno: 20/12/2019
doi: 10.5937/savteh1902046N
Razvoj i karakterizacija raznih katjonskih sorbenata na bazi lignocelulozne kore tikvice
aUniverzitet u Nišu, Tehnološki fakultet, Leskovac
bHigh Technological and Artistic School, Leskovac
cUniverzitet u Nišu, Prirodno-matematički fakultet, Odsek Hemija

e-adresa: goranchem_yu@yahoo.com

Projekat

Biljni i sintetički bioaktivni proizvodi novije generacije (MPNTR - 34012)

Sažetak

Cilj ove studije je razvoj različitih katjonskih sorbenata na bazi lignocelulozne biomase ploda Lagenaria vulgaris, sa svojstvom efikasne sorpcije anjonskih polutanata iz vodenih rastvora. U tom smislu, za sintezu katjonskih sorbenata ispitana je i korišc'ena lignocelulozna kora tikvice (LGS biomasa), koja predstavlja potencijalno dragoceni poljoprivredni otpad. Priprema odgovarajućeg prekursora sinteze (LVAT) izvršena je alkalnim predtretmanom LGS biomase. Predtretman biomase u slabo alkalnim uslovima, pomoću zelenog karbonatnog rastvora, izvođen je radi delimične delignifikacije i ekstrakcije depolimerizovane hemiceluloze. Na ovajnačin se postiže veća poroznost materijala i aktiviranje dostupnih celuloznih mikrofibrila, što je od značaja za efikasniju sintezu sorbenta većeg afiniteta i sorpcionog kapaciteta za anjonske vrste. Aktivacija podrazumeva prevođenje raspoloživih -OH funkcionalnih grupa do -ONa forme (alkali-celuloza), uz održanje polazne konstitucije biomase. Aktivirani prekursor je pogodniji za uspešnije izvođenje reakcije eterifikacije organskim halogenidom, a potom katjonizovanja odgovarajućim Nreagensima. Sinteza katjonskih sorbenata vršena je na tri načina. Za katjonsku modifikaciju LGS biomase i LVAT prekursora, korišc'eni su različiti N-reagensi, poput tercijarnih amino i kvaternernih amonijum jedinjenja, radi utvrđivanja uticaja strukture i hidrofobnosti reagensa na ishod sinteze, a pre svega na sorpciona svojstva dobijenih sorbenata. Sintetisani katjonski sorbenti su okarakterisani fizičkohemijskim metodama i testirani za uklanjanje anjonskih polutanata iz vode, pre svega fosfata i nitrata. Različite hemijske modifikacije lignocelulozne biomase primenjene u ovim istraživanjima pružaju naučni doprinos boljem razumevanju samog mehanizma procesa sorpcije anjona na površini sorbenta.

Ključne reči

biomasa; kora tikvice; katjonski sorbenti; anjonski polutanti; tretman otpadnih voda

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