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2017, vol. 58, br. 3, str. 369-376
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Dekolorizacija obojene otpadne vode pomoću sorbenta napravljenog od prirodnih celuloznih vlakana
Environmental protection from emissions of colored waste water by natural sorbent made from cellulose fibers
aUniverzitet u Nišu, Tehnološki fakultet, Leskovac, Srbija bUniverzitet u Beogradu, Tehnički fakultet u Boru, Srbija cVisoka tehnološko umetnička strukovna škola Leskovac, Leskovac
e-adresa: drag_64@yahoo.com
Sažetak
Ovaj rad se bavi zaštitom okoline od emisije obojene otpadne vode tekstilne industrije. Radi se o obezbojavanju uz pomoć sorbenta dobijenog od prirodnih celuloznih otpadnih vlakana pamuka i konoplje. Uklanjanje reaktivne boje sorbentom iz vodenog rastvora ispitivano je pod različitim uslovima. Utvrđeno je da adsorpcija zavisi od vremena kontaktiranja, početne koncentracije boje i pH rastvora. Korišćeni sorbent je relativno fino rasuti materijal sa heterogenim poroznim česticama, razuđenog oblika i forme, dimenzija ispod 0,7 mm. Prema rezultatima kvantitativnog sastava sorbenta zaključuje se da dominira ugljenik, količina ugljenika 67,26 %. Maksimum stepena uklanjanja boje dešava pri pH 2-3 (68,5 %). Adsorbovana količine boje na sorbentu sa vremenom raste sa povećanjem početne koncentracije. Izotermni modeli, Langmuir i Freundlich, vrlo dobro opisiju uklanjanje reaktivne boje iz vodenog rastvora uz pomoć sorbenta (koeficijenti determinacija = ili > 0,9), u z činjenicu da se prednost daje nelinearnom modelu Freundlich - a koji najbolje opisuje eksperimentalne podatke.
Abstract
Environment protecting from emissions of colored waste water of the textile industry is the subject of this paper. It's about the decolorization with the help of sorbent obtained from natural cellulose fiber waste cotton and hemp. Removal of reactive dye from an aqueous solution by the sorbent was examined under different conditions. It was found that adsorption depends on the contact time, initial dye concentrations and pH of the solution. The used sorbent is a relatively fine dispersion material with heterogeneous porous particles, the diverse shapes and forms, dimensions below 0.7 mm. According to the results of the quantitative composition of the sorbent it is concluded that dominates the carbon, carbon content 67.26 %. The maximum degree of dye removal occurs at pH 2-3 (68.5 %). The adsorbed amount of dye on the sorbent over time increases with increasing initial concentration. Isothermal models, Langmuir and Freundlich, very well describe the removal of reactive dye from aqueous solution with the help of sorbent (coefficients of determination = or > 0.9), with the notion that advantage is given to the nonlinear Freundlich model that best describes experimental data.
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