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Zaštita materijala
2019, vol. 60, br. 3, str. 229-236
O sintezi 3-cijano-6-hidroksi-4-metil-2-piridona na sobnoj temperaturi
Zdujić Miodrag V.a ORCID, Petrović Slobodan D.b, Valentić Nataša V.b ORCID, Mijin Dušan Ž.b ORCID
aSrpska akademija nauke i umetnosti (SANU), Institut tehničkih nauka, Beograd, Srbija
bUniverzitet u Beogradu, Tehnološko-metalurški fakultet, Srbija

e-adresa: kavur@tmf.bg.ac.rs
Projekat:
Proučavanje sinteze, strukture i aktivnosti organskih jedinjenja prirodnog i sintetskog porekla (MPNTR - 172013)
Nanostrukturni funkcionalni i kompozitni materijali u katalitičkim i sorpcionim procesima (MPNTR - 45001)

Ključne reči: cijanoacetamid; acetsirćetni estar; mehanohemijska sinteza; planetarni mlin sa kuglama; optimizacija
Sažetak
Mlevenje cijanoacetoamida (2) i acetsirćetnog estra (1) kao reaktanata, u prisustvu KOH kao katalizatora i etanola kao agensa kojim se kontroliše viskoznost, izvedeno je u planetarnom mlinu radi ispitivanja mogućnosti mehanohemijske sinteze 3-cijano-6-hidroksi-4-metil-2-piridona (3) na sobnoj temperaturi. Mehanohemijski tretman je izveden sa različitim parametrima mlevenja: vremenom mlevenja do 4 h, različitom veličinom i brojem kuglica, različitom brzinom obrtanja, kao i različitim molarnim odnosom reaktanata i katalizatora. Dobijeni proizvod je okarakterisan određivanjem temperature topljenja, UV, IR i NMR analizama. Nađeno je da je dominantni procesni parametar vreme mlevenja, dok su ostali od manjeg uticaja. Najveći prinos izolovanog proizvoda je oko 56%, dok se naknadnim "odležavanjem" prinos povećava preko 60%.
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O članku

jezik rada: engleski
vrsta rada: naučni članak
DOI: 10.5937/zasmat1903229Z
objavljen u SCIndeksu: 25.12.2019.
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