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2022, vol. 63, br. 3, str. 238-250
Adsorpcijski i inhibitorski uticaj 5-[4-(dimetilamino) benziliden] - 1,3-dimetilbarbiturne kiseline na koroziju ugljeničnog čelika u molarnom rastvoru hlorovodonične kiseline
Mansoura University, Faculty of Science, Department of Chemistry, Mansoura, Egypt

e-adresaasfouda@mans.edu.eg
Ključne reči: ugljenični čelik; HCl; EFM; EIS; derivat 5-ariliden barbiturne kiseline
Sažetak
IInhibicijski uticaj ekološki prihvatljive 5-[4-(dimetilamino) benziliden -1, -dimetil barbiturne kiseline u 1M HCl na koroziju ugljeničnog čelika je ispitan pomoću metoda gubitka težine (VL), potenciodinamičke polarizacije (PP), elektrohemijske impedansne spektroskopije (EIS) i testova elektrohemijske frekvencijske modulacije (EFM). Postignuti rezultati pokazuju da je ispitivano jedinjenje odličan inhibitor i da se njegova efikasnost inhibicije (%IE) povećava povećanjem koncentracije i smanjuje povećanjem temperature. Adsorpcija 5-ariliden barbiturne kiseline na površini ugljeničnog čelika prati Langmuirovu izotermu. Proces adsorpcije ispitivanog jedinjenja je spontan i smatra se hemisorpcionim. PP krive su otkrile da je derivat 5-ariliden barbiturne kiseline inhibitor mešovitog tipa. Štaviše, rezultati EIS-a su potvrdili adsorpciju ispitivanog jedinjenja na površini ugljeničnog čelika kroz povećanje otpora prenosa naelektrisanja (Rct). IE% ovog inhibitora dostigao je 86,9% pri koncentraciji 21×10-6 M prema PP metodi. Konačno, eksperimentalni i teorijski rezultati su u dobroj harmoniji.
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O članku

jezik rada: engleski
vrsta rada: naučni članak
DOI: 10.5937/zasmat2203238A
primljen: 07.02.2022.
prihvaćen: 05.03.2022.
objavljen u SCIndeksu: 03.09.2022.
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