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Zaštita materijala
2020, vol. 61, br. 4, str. 286-305
Elektrohemijsko ponašanje pri zaštiti od korozije mekog čelika (MS) u 1M HCl kiselini upotrebom leka lidokain kao inhibitora
Adel Ali H.a, Abd El-Aziz Fouda S.b, Amal Tilp H.c
aTaiz University, Faculty of Science branch of Al-torba, Department of Physics, Yemen
bEl-Mansoura University, Faculty of Science, Department of Chemistry, El-Mansoura, Egypt
cQassim University, College of Science, Chemistry Department, Qassim, Buraydah, Saudi Arabia + Ain Shams University, Faculty of Girls, Arts, Science & Education, Chemistry Department, Buraydah, Egypt

e-adresa: asfouda@mans.edu.eg
Sažetak
Lidokain, kao inhibitor korozije za zaštitu mekog čelik (MS) u 1M HCl, proučavan je ispitivanjem gubitka težine (VL), procene vodonika (HE), potencijala otvorenog kola (EOCP), potenciodinamičke polarizacije (PP), elektrohemijske impedansne spektroskopije (EIS) i elektrohemijske frekvencijske modulacije (EFM). Gubitak težine proučavan je na različitim temperaturama između (25 - 450C) a procena vodonika i elektrohemijska ispitivanja na sobnoj temperaturi. Proučavan je uticaj temperature na inhibiciju korozije i izračunati termodinamički parametri aktivacije. Mofologija MS ispitivana je pomoću skenirajućeg elektronskog mikroskopa sa tehnologijom disperzivne rentgenske spektroskopije (SEM - EDKS) i atomskom mikroskopijom (AFM). Tehnika elektrohemijske impedance je pokazala da prisustvo leka lidokaina u rastvoru smanjuje dvoslojni kapacitet i povećava otpor prenosa naelektrisanja. Utvrđeno je da adsorpcija lidokaina na površini Ms podleže izotermi Langmuir adsorpcije i razjašnjava mehanizam inhibicije korozije. Izračunati su parametri adsorpcije i utvrđeno je da lek lidokain deluje kao inhibitor mešovitog tipa. Sva površinska ispitivanja i analize potvrđuju formiranje tankog filma koji je prekrio površinu metala i sprečava koroziju površine metala.
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O članku

jezik rada: engleski
vrsta rada: naučni članak
DOI: 10.5937/zasmat2004286A
primljen: 15.06.2020.
prihvaćen: 13.07.2020.
objavljen u SCIndeksu: 05.02.2021.
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