Metrika

  • citati u SCIndeksu: 0
  • citati u CrossRef-u:0
  • citati u Google Scholaru:[]
  • posete u poslednjih 30 dana:9
  • preuzimanja u poslednjih 30 dana:6

Sadržaj

članak: 6 od 57  
Back povratak na rezultate
2020, vol. 70, br. 3, str. 11-16
Istraživanje direktne elektrohemijske oksidacije neonikotinoidnog pesticida tiametoksam u vodi
aUniverzitet u Beogradu, Tehnološko-metalurški fakultet
bUniverzitet odbrane, Vojna akademija, Beograd
cInstitut za pesticide i zaštitu životne sredine, Beograd

e-adresastevan.stupar13@gmail.com
Projekat:
The research covered in this paper was carried out in the framework of the University of Defense, Project No. VATT/1/18-20

Ključne reči: elektrohemijska oksidacija; pesticidi; kinetički parametri; IrOX anoda; potrošnja energije; UV/Vis spektroskopija
Sažetak
Poslednjih decenija očigledna je sve veća upotreba hemikalija na mnogo načina u savremenom životu. Stoga je mogućnost njegovog unosa u organizme, trovanja ljudi i životinja i oštećenja zdravlja, danas na visokom nivou, posebno kada su u pitanju katastrofe izazvane upotrebom toksičnih hemikalija u terorističkim napadima ili u vojne svrhe. Ako gledamo unapred, rizik od zagađenja vode i tla pesticidima, kao jednima od najvažnijih resursa za preživljavanje, uvek je prisutan. Široki spektri negativnih efekata pesticida na životnu sredinu iniciraju sve veći broj ispitivanja efikasnih metoda uklanjanja pesticida, posebno iz vode. Cilj ovog rada bio je da se ispita efikasnost direktne elektrohemijske oksidacije kao metoda za insitu razgradnju pesticida u vodenoj sredini, u zavisnosti od koncentracije pesticida, prisutnih elektrolita, primenjene struje i pH vrednosti medijuma. Kao model molekula korišćen je neonikotinoidni pesticid tiametoksam. Kinetika razgradnje tiametoksama u vodenom rastvoru praćena je UV/Vis spektrometrijom.
Reference
Adrian, T., Chiorcea-Paquim, A., Fatibello-Filho, O., Oliveira-Brett, A.M. (2009) Electrochemistry Communications Hydroxyl radicals electrochemically generated in situ on a borondoped diamond electrode. Electrochemistry Communications, 11(7): 1342-1345
Aksu, Z. (2005) Application of biosorption for the removal of organic pollutants: A review. Process Biochemistry, 40: 997-1026
Anjum, R., Malik, A. (2013) Evaluation of mutagenicity of wastewater in the vicinity of pesticide industry. Environmental Toxicology and Pharmacology, 35(2): 284-291
Awad, H.S., Galwa, N.A. (2005) Electrochemical degradation of Acid Blue and Basic Brown dyes on Pb/PbO2 electrode in the presence of different conductive electrolyte and effect of various operating factors. Chemosphere, 61(9): 1327-1335
Badawy, M.I., Ghaly, M.Y., Gad-Allah, T.A. (2006) Advanced oxidation processes for the removal of organophosphorus pesticides from wastewater. Desalination, 194: 166-175
Badellino, C., Rodrigues, C.A., Bertazzoli, R. (2006) Oxidation of pesticides by in situ electrogenerated hydrogen peroxide: Study for the degradation of 2,4-dichlorophenoxyacetic acid. Journal of Hazardous Materials, 137(2): 856-864
Bass, C., Denholm, I., Williamson, M.S., Nauen, R. (2015) The global status of insect resistance to neonicotinoid insecticides. Pesticide Biochemistry and Physiology, 121: 78-87
Calderbank, A. (1978) Chapter 6: Organophosphorus Insecticides. u: Peacock F.C. [ur.] Jealott's Hill: Fifty years of Agricultural Research 1928-1978, Imperial Chemical Industries Ltd
Dugandžić, A.M., Tomašević, A.V., Radišić, M.M., Šekuljica, N., Mijin, D., Petrović, S.D. (2017) Effect of inorganic ions, photosensitisers and scavengers on the photocatalytic degradation of nicosulfuron. Journal of Photochemistry and Photobiology A: Chemistry, 336: 146-155
Guzman-Duque, F.L., Palma-Goyes, R.E., Gonzalez, I., Penuela, G., Torres-Palma, R.A. (2014) Relationship between anode material, supporting electrolyte and current density during electrochemical degradation of organic compounds in water. Journal of Hazardous Materials, 278: 221-226
Hachami, F., Errami, M., Bazzi, L., Hilali, M., Salghi, R., Jodeh, S., Hammouti, B., Hamed, O. (2015) A comparative study of electrochemical oxidation of methidation organophosphorous pesticide on SnO2 and boron-doped diamond anodes. Chemistry Central Journal, 9(59): 1-7
He, S., Huang, Q., Zhang, Y., Wang, L., Nie, Y. (2015) Investigation on Direct and Indirect Electrochemical Oxidation of Ammonia over Ru-Ir/TiO2 Anode. Industrial & Engineering Chemistry Research, 54(5): 1447-1451
L.I.C., Xie, Y., Guo, Y., Cheng, Y., Y.U.H., Qian, H., Yao, W. (2020) Effects of ozone-microbubble treatment on the removal of residual pesticides and the adsorption mechanism of pesticides onto the apple matrix. Food Control, 120: 107548
Lebik-Elhadi, H., Frontistis, Z., Ait-Amar, H., Amrani, S., Mantzavinos, D. (2018) Electrochemical oxidation of pesticide thiamethoxam on boron doped diamond anode: Role of operating parameters and matrix effect. Process Safety and Environmental Protection, 116: 535-541
Lu, L.A., Mab, Y.S., Kumar, M., Lin, J.G. (2011) Photo-Fenton pretreatment of carbofuran - Analyses via experimental design, detoxification and biodegradability enhancement. Separation and Purification Technology, 81(3): 325-331
Malakootian, M., Shahesmaeili, A., Faraji, M., Amiri, H. (2020) Advanced oxidation processes for the removal of organophosphorus pesticides in aqueous matrices: A systematic review and meta-analysis. Process Safety and Environmental Protection, 134: 292-307
Martínez-Huitle, C.A., Ferro, S. (2006) Electrochemical oxidation of organic pollutants for the wastewater treatment: direct and indirect processes. Chemical Society Reviews, 35(12): 1324-1340
Periasamy, A., Muruganand, S., Palaniswamy, M. (2009) Vibrational studies of Na 2 SO 4 , K 2 SO 4 , NaHSO 4 and KHSO 4 crystals. Rasayan Journal of Chemistry, 2(4): 981-989
Raloff, J. (1984) Agent Orange and Birth Defects Risk. Science News, 126(8): 117
Saleh, I.A., Zouari, N., Al-Ghouti, M.A. (2020) Removal of pesticides from water and wastewater: Chemical, physical and biological treatment approaches. Environmental Technology & Innovation, 19: 101026
Silonardo, J., Vieira, L., Carvalho, W., Benvindo-Souza, M. (2020) Mutagenic, genotoxic and morphotoxic potential of different pesticides in the erythrocytes of Podocnemis expansa neonates. Science of the Total Environment, 737: 140304
Stupar, S., Grgur, B.N., Onjia, A.E., Mijin, D. (2017) Direct and indirect electrochemical degradation of acid blue 111 using IrOX anode. International Journal of Electrochemical Science, 12(9): 8564-8577
Tarique, M., Kumar, M., Malik, A. (2019) Mutagenicity , genotoxicity and oxidative stress induced by pesticide industry wastewater using bacterial and plant bioassays. Biotechnology Reports, 24: e00389
Tokuda, Y., Kikuchi, M., Takahashi, O. (2006) Prehospital management of sarin nerve gas terrorism in urban settings: 10 years of progress after the Tokyo subway sarin attack. Resuscitation, 68(2): 193-202
Tucker, C.S. (2011) The Encyclopedia of the Vietnam War: a Political, Social and Military History. Defoliation, 2nd ed
Wang, A., Mahai, G., Wan, Y., Jiang, Y., Meng, Q., Xia, W., H.E.Z., X.U.S. (2019) Neonicotinoids and carbendazim in indoor dust from three cities in China: Spatial and temporal variations. Science of The Total Environment, 695: 133790
Wang, H., Tang, C., Yang, J., Wang, N., Jiang, F., Xia, Q. (2018) Predictors of urinary antibiotics in children of Shanghai and health risk assessment. Environment International, 121: 507-514
Wang, T., A.I.S., Zhou, Y., Luo, Z., Dai, C., Yang, Y., Zhang, J., Huang, H., Luo, S., Luo, L. (2018) Adsorption of agricultural wastewater contaminated with antibiotics, pesticides and toxic metals by functionalized magnetic nanoparticles. Journal of Environmental Chemical Engineering, 6(5): 6468-6478
Wang, Y., Wang, S., Xie, T., Cao, J. (2020) Activated carbon derived from waste tangerine seed for the high-performance adsorption of carbamate pesticides from water and plant. Bioresource Technology, 316: 123929
Wang, Z., Brooks, B.W., Zeng, E.Y., You, J. (2019) Comparative mammalian hazards of neonicotinoid insecticides among exposure durations. Environment International, 125: 9-24
Yao, Y., Teng, G., Yang, Y., Huang, C., Liu, B., Guo, L. (2018) Electrochemical oxidation of acetamiprid using Yb-doped PbO2 electrodes: Electrode characterization, influencing factors and degradation pathways. Separation and Purification Technology, 211: 456-466
Zhang, F., Feng, C., Li, W., Cui, J. (2014) Indirect Electrochemical Oxidation of Dye Wastewater Containing Acid Orange 7 Using Ti / RuO 2 -Pt Electrode. International Journal of Electrochemical Science, 9: 943-954
Zhang, F., Zhang, Y., Ni, H., Ma, K., Li, R. (2014) Experimental and DFT studies on the vibrational, electronic spectra and NBO analysis of thiamethoxam. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 118: 162-171
 

O članku

jezik rada: engleski
vrsta rada: neklasifikovan
DOI: 10.5937/str2003011S
primljen: 29.10.2020.
prihvaćen: 18.11.2020.
objavljen u SCIndeksu: 09.04.2021.
Creative Commons License 4.0